Interferometry#

Ice thickness is determined by in-situ laser measurment (e.g. HeNe laser with a fixed wavelength of Ī»0 = 632.8 nm). The laser beam is positioned so that it reflects off the centre of the substrate and the reflected beam is measured with a photodiode

Note

  • Include diagram of the setup
    • position of the laser
    • position of the detector
As monochromatic light is shone onto an ice film, the light can be reflected from the vacuum-ice interface or the ice-substrate interface. The reflected light sin-waves interacts and interference patterns appears due to the constructive and destructive interference arising from the increasing ice thickness as shown in Fig. 1.
../../../_images/Thickness_1_Rachel.png

Fig. 1 Taken from Rachael, to redo#

Note

  • add svg sin wave to show constructive, destructive interference
\[y = y_0 + A sin(\frac{2\pi}{w}(x-x_c))\]

where \(y_0\) is the vertical offset, \(A\) is the amplitude, \(x_c\) is the horizontal offset and \(w\) is the period (i.e. \(2\pi/w\) is the frequency).

We define the sine function ā€˜sinfit(x, *p)ā€™ for the fit with some initial guesses, which can be edited accordingly.

  • A is obtained from the fit

Ice Refractive index#

Theory#

  • Symbol: n

It is used to describe the optical properties of a pure medium and is a complex function of two parameters:

  • k imaginary index - describe the attenuation or the absorbtion of the medium
  • n real refractive index - it is the ratio of the velocity of light within the mediumwith respect to the speed of light in vacuum

Both k and n are wavelength dependant, hence require investigation over the whole electromagnetic spectrum:

  • []: UV investigation (Amorphous and crystaline water ice)

Warning

  • How does ice porosity affect the refractive index
  • How has he been determined in the IR range.
    • Should I use value of the litterature rather than the laser diode signal ?

Then we can estimate the refractive index of the ice (n2), can be estimated using the following equation

\[n_2 = \frac{y_0 + A}{y_0 - A}\]

Using Snellā€™s Laaw (\(n_1 sinĪø_1 = n_2 sinĪø_2\))

\[Īø_2 = sin^{-1} (\frac{n_1 sinĪø_1}{n_2})\]
\[d_{fringe} = \frac{Ī»_0}{n_2 cosĪø_2}\]

Warning

Difference in fitting from different molecules

  • single vs binary mixtures

To see how this is translated into code visit the folloing page []